2016年2月16日星期二
Silane coupling agent migration method
The silane coupling agent
directly added to the adhesive composition, as the matrix resin for the
amount of general amount of 1 ~ 5%.After the glue by molecular
diffusion effect, coupling agent molecular migration to the bonding
interface coupling effect.For curing adhesives, glue should be placed
after a period of time for curing, so that the coupling agent to
complete the migration process, in order to obtain good results.Actual
use, often coupling agent on the surface to form a sediment, but the
real work is monomolecular layer, therefore, the dosage of coupling
agent need not too much.The method using silane coupling agent surface
pretreatment method and direct addition method, the former is diluted
with coupling agent treatment filler surface, which is a premixed resin
and filler, adding coupling agent of concentrate.Silane coupling agent
into the solution, is advantageous to the silane coupling agent on the
surface of the material, dispersion, solvent is a mixture of water and
alcohol solution, the solution is commonly silane (20%), alcohol (72%),
water (8%), alcohol is commonly ethanol (to ethoxy silane) methanol
(methoxy silane) and isopropanol (to not easily soluble in ethanol,
methanol silane) by silane hydrolysis velocity is related to PH value,
the slowest neutral, acid, alkali is faster, so generally need to adjust
the PH value of solution, in addition to the amino silane, other silane
can add a small amount of acetic acid, adjusting the PH to 4, 5, amino
silane for alkaline, don't have to be adjusted.Because of silane
hydrolysis, not far, had better match current now, best finished in an
hour.
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